p-Block Elements NEET PYQs – Chapter-wise MCQs with Answers

p-Block Elements NEET Previous Year Questions (PYQs)

Practice NEET previous year questions from p-Block Elements (Group 13–18). These MCQs cover boron family, carbon family, nitrogen, oxygen, halogens and noble gases with answers and clear explanations strictly based on NCERT.

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p-Block Elements Chapter Notes


Q1. Which one of the following elements is unable to form BF6− ion?

(NEET 2018)

  • (A) Al
  • (B) Ga
  • (C) In
  • (D) B
Show Answer

(D)

Show Explanation

Boron does not have vacant d-orbitals and cannot expand its octet.


Q2. Boric acid is acidic because it:

(NEET 2016)

  • (A) contains replaceable H+
  • (B) donates a proton
  • (C) accepts OH− from water
  • (D) combines with H+
Show Answer

(C)

Show Explanation

Boric acid acts as a Lewis acid by accepting OH− ion from water.


Q3. The stability of +1 oxidation state among Al, Ga, In and Tl increases in the order:

(NEET 2015)

  • (A) Al < Ga < In < Tl
  • (B) Tl < In < Ga < Al
  • (C) Ga < Al < In < Tl
  • (D) In < Tl < Ga < Al
Show Answer

(A)

Show Explanation

Inert pair effect increases down the group, stabilising +1 oxidation state.


Q4. Which compound has a structure similar to graphite?

(NEET 2013)

  • (A) SiC
  • (B) AlN
  • (C) BN
  • (D) B2O3
Show Answer

(C)

Show Explanation

BN is known as inorganic graphite and has layered structure.


Q5. The basic structural unit of silicates is:

(NEET 2013)

  • (A) SiO2
  • (B) SiO44−
  • (C) Si2O76−
  • (D) SiO32−
Show Answer

(B)

Show Explanation

All silicates are built from SiO44− tetrahedra.


Q6. Which oxide is amphoteric?

(NEET 2011)

  • (A) Al2O3
  • (B) CO2
  • (C) SO3
  • (D) Na2O
Show Answer

(A)

Show Explanation

Al2O3 reacts with both acids and bases.


Q7. Which hydride acts as a Lewis acid?

(NEET 2010)

  • (A) NH3
  • (B) CH4
  • (C) BH3
  • (D) H2O
Show Answer

(C)

Show Explanation

BH3 is electron deficient and accepts electron pairs.


Q8. Which halogen has the highest electron gain enthalpy?

(NEET 2018)

  • (A) F
  • (B) Cl
  • (C) Br
  • (D) I
Show Answer

(B)

Show Explanation

Chlorine has maximum electron gain enthalpy due to optimal size.


Q9. Strong reducing behaviour of H3PO2 is due to:

(NEET 2015)

  • (A) two P–OH bonds
  • (B) two P–H bonds
  • (C) high oxidation state
  • (D) resonance
Show Answer

(B)

Show Explanation

Presence of P–H bonds makes it a strong reducing agent.


Q10. The high boiling point of HF compared to other hydrogen halides is due to:

(NEET 2015)

  • (A) high bond energy
  • (B) hydrogen bonding
  • (C) higher molar mass
  • (D) van der Waals forces
Show Answer

(B)

Show Explanation

Strong intermolecular hydrogen bonding exists in HF.


Q11. Which nitrogen oxide is paramagnetic?

(NEET 1994)

  • (A) N2O
  • (B) NO
  • (C) N2O5
  • (D) NO2
Show Answer

(D)

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NO2 contains one unpaired electron.


Q12. Which of the following does NOT give oxygen on heating?

(NEET 2013)

  • (A) KClO3
  • (B) KMnO4
  • (C) NaNO3
  • (D) NaClO4
Show Answer

(D)

Show Explanation

NaClO4 is very stable and does not decompose easily.


Q13. Which allotrope of phosphorus is most reactive?

(NEET 1999)

  • (A) Red
  • (B) White
  • (C) Black
  • (D) Violet
Show Answer

(B)

Show Explanation

White phosphorus has low ignition temperature.


Q14. Bleaching action of chlorine is due to:

(NEET 1991)

  • (A) reduction
  • (B) oxidation
  • (C) chlorination
  • (D) hydrolysis
Show Answer

(B)

Show Explanation

Chlorine oxidises colouring matter in presence of moisture.


Q15. Which noble gas forms the maximum number of compounds?

(NEET 2019)

  • (A) He
  • (B) Ne
  • (C) Ar
  • (D) Xe
Show Answer

(D)

Show Explanation

Xenon has comparatively lower ionisation energy.


Q16. Which molecule has square planar geometry?

(NEET 2019)

  • (A) XeF2
  • (B) XeF4
  • (C) XeF6
  • (D) XeO3
Show Answer

(B)

Show Explanation

XeF4 has sp3d2 hybridisation with two lone pairs.


Q17. Which hydride shows strongest hydrogen bonding?

(NEET 1992)

  • (A) NH3
  • (B) H2O
  • (C) HF
  • (D) H2S
Show Answer

(C)

Show Explanation

HF has highest electronegativity difference.


Q18. Which gas is absorbed by alkaline pyrogallol?

(NEET 1991)

  • (A) CO2
  • (B) O2
  • (C) N2
  • (D) H2
Show Answer

(B)

Show Explanation

Alkaline pyrogallol absorbs oxygen.


Q19. Which element readily forms anions?

(NEET 1992)

  • (A) Alkali metals
  • (B) Alkaline earth metals
  • (C) Halogens
  • (D) Noble gases
Show Answer

(C)

Show Explanation

Halogens have high electron affinity.


Q20. Which compound is electron deficient?

(NEET 2000)

  • (A) NH3
  • (B) BF3
  • (C) CH4
  • (D) H2O
Show Answer

(B)

Show Explanation

BF3 has only six electrons in valence shell of boron.


👉 More p-Block Elements NEET PYQs will be added gradually.

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